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Table 7 Main bond angles (°) in cationic groups of [C12H17N2]2CdCl4 and [C6H10N2]2[Cd3Cl10] compounds. (Esd are given in parentheses).

From: Synthesis, Infra-red, Raman, NMR and structural characterization by X-ray Diffraction of [C12H17N2]2CdCl4 and [C6H10N2]2Cd3Cl10compounds

Compound (1)

Compound (2)

Angle (°) of C12H17N2+(a)

Angle (°) of C12H17N2+(b)

Angle (°) of C6N2H10

C(13)-C(12)-C(11)

121.9(4)

C(23)-C(22)-C(21)

121.7(4)

C2v-C1-C6vi

120.8(5)

C(14)-C(13)-C(12)

120.4(5)

C(22)-C(23)-C(24)

118.8(4)

C1v-C2-C5vii

119.1(4)

C(15)-C(14)-C(13)

119.6(4)

C(25)-C(24)-C(23)

120.0(3)

C3-C4-C5v

120.2(5)

C(14)-C(15)-C(16)

120.9(4)

C(24)-C(25)-C(26)

123.2(3)

C2vi-C5-C4v

120.9(5)

C(12)-C(11)-C(16)

117.1(3)

C(21)-C(26)-C(25)

115.4(3)

C1vii-C6-C3

119.4(5)

N(11)-C(11)-C(16)

120.4(4)

C(22)-C(21)-C(26)

120.8(3)

C1vii-C6-N2

121.7(4)

C(12)-C(11)-N(11)

122.2(3)

C(26)-C(21)-N(21)

124.7(3)

C3-C6-N2

118.8(4)

C(11)-N(11)-C(17)

122.7(3)

C(22)-C(21)-N(21)

114.4(3)

C2v-C1-N1

118.5(4)

N(11)-C(17)-C(171)

110.4(4)

C(27)-N(21)-C(21)

129.3(4)

C6vi-C1-N1

120.7(4)

N(11)-C(17)-C(172)

108.3(3)

N(21)-C(27)-C(271)

117.5(4)

  

C(172)-C(17)C(171)

109.5(4)

N(21)-C(27)-C(28)

120.1(3)

  

N(11)-C(17)-C(18)

107.8(2)

C(28)-C(27)-C(271)

122.3(3)

  

C(172)-C(17)-C(18)

112.6(4)

C(27)-C(28)-C(29)

115.1(3)

  

C(171)-C(17)-C(18)

108.2(4)

C(291)-C(29)-C(28)

109.7(3)

  

C(19)-C(18)-C(17)

113.1(3)

C(292)-C(29)-C(28)

109.1(3)

  

C(191)-C(19)-C(18)

122.7(4)

C(292)-C(29)-C(291)

111.0(3)

  

N(12)-C(19)-C(18)

117.3(4)

N(22)-C(29)-C(28)

108.9(3)

  

N(12)-C(19)-C(191)

119.8(4)

N(22)-C(29)-C(291)

113.1(4)

  

C(19)-N(12)-C(16)

126.5(3)

N(22)-C(29)-C(292)

104.9(3)

  

N(12)-C(16)-C(11)

120.2(3)

C(26)-N(22)-C(29)

128.6(3)

  

N(12)-C(16)-C(15)

119.6(3)

N(22)-C(26)-C(21)

129.3(3)

  

C(11)-C(16)-C(15)

120.0(4)

N(22)-C(26)-C(25)

115.2(3)

  
  1. - symmetry code : i: -x+1,-y,-z+1; ii: x-1,y,z; iii: -x+2,-y,-z+1; iv: x+1,y,z;
  2. v: -x+2,-y,-z+2; vi: x,y-1,z; vii: x,y+1,z;